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Publication 2: Continuous Flow Synthesis of Indoles by Pd-Mediated Reduction of o-Nitrostilbenes with Carbon Monoxide

发布时间:2022-03-23 11:27:56浏览:1017次

Kappe Pd Indoles.jpg

The Pd-mediated reduction of o-nitrostilbenes in the presence of carbon monoxide is reported to proceed regioselectively under pressurised flow-through conditions to cleanly afford indoles.

A variety of substrates are tolerated and the reaction proceeds significantly faster  than in batch and produces carbon dioxide as the only stoichiometric side-product.

Publication 61Continuous Flow Synthesis of Indoles by Pd-Mediated Reduction of o-Nitrostilbenes with Carbon Monoxide.pdf


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